Inverted bulk-heterojunction solar cell with cross-linked hole-blocking layer.
Identifieur interne : 000128 ( Main/Exploration ); précédent : 000127; suivant : 000129Inverted bulk-heterojunction solar cell with cross-linked hole-blocking layer.
Auteurs : RBID : pubmed:24817837Abstract
We have developed a hole-blocking layer for bulk-heterojunction solar cells based on cross-linked polyethylenimine (PEI). We tested five different ether-based cross-linkers and found that all of them give comparable solar cell efficiencies. The initial idea that a cross-linked layer is more solvent resistant compared to a pristine PEI layer could not be confirmed. With and without cross-linking, the PEI layer sticks very well to the surface of the indium-tin-oxide electrode and cannot be removed by solvents used to process PEI or common organic semiconductors. The cross-linked PEI hole-blocking layer functions for multiple donor-acceptor blends. We found that using cross-linkers improves the reproducibility of the device fabrication process.
DOI: 10.1016/j.orgel.2014.02.009
PubMed: 24817837
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Inverted bulk-heterojunction solar cell with cross-linked hole-blocking layer.</title><author><name sortKey="Udum, Yasemin" uniqKey="Udum Y">Yasemin Udum</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria ; Institute of Science and Technology, Department of Advanced Technologies, Gazi University, 06570 Ankara, Turkey.</nlm:affiliation><country xml:lang="fr">Turquie</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria ; Institute of Science and Technology, Department of Advanced Technologies, Gazi University, 06570 Ankara</wicri:regionArea></affiliation></author><author><name sortKey="Denk, Patrick" uniqKey="Denk P">Patrick Denk</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author><author><name sortKey="Adam, Getachew" uniqKey="Adam G">Getachew Adam</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author><author><name sortKey="Apaydin, Dogukan H" uniqKey="Apaydin D">Dogukan H Apaydin</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author><author><name sortKey="Nevosad, Andreas" uniqKey="Nevosad A">Andreas Nevosad</name><affiliation wicri:level="1"><nlm:affiliation>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben</wicri:regionArea></affiliation></author><author><name sortKey="Teichert, Christian" uniqKey="Teichert C">Christian Teichert</name><affiliation wicri:level="1"><nlm:affiliation>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben</wicri:regionArea></affiliation></author><author><name sortKey="S White, Matthew" uniqKey="S White M">Matthew S White</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author><author><name sortKey="S Sariciftci, Niyazi" uniqKey="S Sariciftci N">Niyazi S Sariciftci</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author><author><name sortKey="Scharber, Markus C" uniqKey="Scharber M">Markus C Scharber</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</nlm:affiliation><country xml:lang="fr">Autriche</country><wicri:regionArea>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><date when="2014">2014</date><idno type="doi">10.1016/j.orgel.2014.02.009</idno><idno type="RBID">pubmed:24817837</idno><idno type="pmid">24817837</idno><idno type="wicri:Area/Main/Corpus">000008</idno><idno type="wicri:Area/Main/Curation">000008</idno><idno type="wicri:Area/Main/Exploration">000128</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">We have developed a hole-blocking layer for bulk-heterojunction solar cells based on cross-linked polyethylenimine (PEI). We tested five different ether-based cross-linkers and found that all of them give comparable solar cell efficiencies. The initial idea that a cross-linked layer is more solvent resistant compared to a pristine PEI layer could not be confirmed. With and without cross-linking, the PEI layer sticks very well to the surface of the indium-tin-oxide electrode and cannot be removed by solvents used to process PEI or common organic semiconductors. The cross-linked PEI hole-blocking layer functions for multiple donor-acceptor blends. We found that using cross-linkers improves the reproducibility of the device fabrication process.</div></front></TEI><pubmed><MedlineCitation Status="Publisher" Owner="NLM"><PMID Version="1">24817837</PMID><DateCreated><Year>2014</Year><Month>5</Month><Day>12</Day></DateCreated><Article PubModel="Print"><Journal><ISSN IssnType="Print">1566-1199</ISSN><JournalIssue CitedMedium="Print"><Volume>15</Volume><Issue>5</Issue><PubDate><Year>2014</Year><Month>May</Month></PubDate></JournalIssue><Title>Organic electronics</Title><ISOAbbreviation>Org Electron</ISOAbbreviation></Journal><ArticleTitle>Inverted bulk-heterojunction solar cell with cross-linked hole-blocking layer.</ArticleTitle><Pagination><MedlinePgn>997-1001</MedlinePgn></Pagination><Abstract><AbstractText NlmCategory="UNLABELLED">We have developed a hole-blocking layer for bulk-heterojunction solar cells based on cross-linked polyethylenimine (PEI). We tested five different ether-based cross-linkers and found that all of them give comparable solar cell efficiencies. The initial idea that a cross-linked layer is more solvent resistant compared to a pristine PEI layer could not be confirmed. With and without cross-linking, the PEI layer sticks very well to the surface of the indium-tin-oxide electrode and cannot be removed by solvents used to process PEI or common organic semiconductors. The cross-linked PEI hole-blocking layer functions for multiple donor-acceptor blends. We found that using cross-linkers improves the reproducibility of the device fabrication process.</AbstractText></Abstract><AuthorList><Author><LastName>Udum</LastName><ForeName>Yasemin</ForeName><Initials>Y</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria ; Institute of Science and Technology, Department of Advanced Technologies, Gazi University, 06570 Ankara, Turkey.</Affiliation></Author><Author><LastName>Denk</LastName><ForeName>Patrick</ForeName><Initials>P</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author><Author><LastName>Adam</LastName><ForeName>Getachew</ForeName><Initials>G</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author><Author><LastName>Apaydin</LastName><ForeName>Dogukan H</ForeName><Initials>DH</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author><Author><LastName>Nevosad</LastName><ForeName>Andreas</ForeName><Initials>A</Initials><Affiliation>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben, Austria.</Affiliation></Author><Author><LastName>Teichert</LastName><ForeName>Christian</ForeName><Initials>C</Initials><Affiliation>Institute of Physics, Montanuniversitaet Leoben, Franz-Josef-Straße 18, 8700 Leoben, Austria.</Affiliation></Author><Author><LastName>S White</LastName><ForeName>Matthew</ForeName><Initials>M</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author><Author><LastName>S Sariciftci</LastName><ForeName>Niyazi</ForeName><Initials>N</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author><Author><LastName>Scharber</LastName><ForeName>Markus C</ForeName><Initials>MC</Initials><Affiliation>Institute for Organic Solar Cells, Johannes Kepler University Linz, Altenbergerstrasse 69, 4040 Linz, Austria.</Affiliation></Author></AuthorList><Language>ENG</Language><PublicationTypeList><PublicationType>JOURNAL ARTICLE</PublicationType></PublicationTypeList></Article><MedlineJournalInfo><MedlineTA>Org Electron</MedlineTA><NlmUniqueID>101588591</NlmUniqueID><ISSNLinking>1566-1199</ISSNLinking></MedlineJournalInfo><KeywordList Owner="NOTNLM"><Keyword MajorTopicYN="N">Device design</Keyword><Keyword MajorTopicYN="N">Electrical contact</Keyword><Keyword MajorTopicYN="N">Organic solar cell</Keyword><Keyword MajorTopicYN="N">Stability</Keyword></KeywordList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2013</Year><Month>11</Month><Day>3</Day></PubMedPubDate><PubMedPubDate PubStatus="revised"><Year>2014</Year><Month>2</Month><Day>10</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2014</Year><Month>2</Month><Day>11</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2014</Year><Month>5</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2014</Year><Month>5</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>5</Month><Day>13</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1016/j.orgel.2014.02.009</ArticleId><ArticleId IdType="pii">S1566-1199(14)00047-0</ArticleId><ArticleId IdType="pubmed">24817837</ArticleId><ArticleId IdType="pmc">PMC4010259</ArticleId></ArticleIdList><pmc-dir>pmcsd</pmc-dir>
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